## Time capsule at the Dibner Library

The first time I met Lilla Vekerdy, she was holding a book.

“A second edition of Galileo’s Siderius nuncius. Here,” she added, thrusting the book into my hands. “Take it.”

So began my internship at the Smithsonian Institution’s Dibner Library for the History of Science and Technology.

Many people know the Smithsonian for its museums. The Smithsonian, they know, houses the ruby slippers worn by Dorothy in The Wizard of Oz. The Smithsonian houses planes constructed by Orville and Wilbur Wright, the dresses worn by First Ladies on presidential inauguration evenings, a space shuttle, and a Tyrannosaurus Rex skeleton. Smithsonian museums line the National Mall in Washington, D.C.—the United States’ front lawn—and march beyond.

Most people don’t know that the Smithsonian has 21 libraries.

Lilla heads the Smithsonian Libraries’ Special-Collections Department. She also directs a library tucked into a corner of the National Museum of American History. I interned at that library—the Dibner—in college. Images of Benjamin Franklin, of inventor Eli Whitney, and of astronomical instruments line the walls. The reading room contains styrofoam cushions on which scholars lay crumbling rare books. Lilla and the library’s technician, Morgan Aronson, find references for researchers, curate exhibitions, and introduce students to science history. They also care for the vault.

The vault. How I’d missed the vault.

A corner of the Dibner’s reading room and part of the vault

The vault contains manuscripts and books from the past ten centuries. We handle the items without gloves, which reduce our fingers’ sensitivities: Interpose gloves between yourself and a book, and you’ll raise your likelihood of ripping a page. A temperature of 65°F inhibits mold from growing. Redrot mars some leather bindings, though, and many crowns—tops of books’ spines—have collapsed. Aging carries hazards.

But what the ages have carried to the Dibner! We1 have a survey filled out by Einstein and a first edition of Newton’s Principia mathematica. We have Euclid’s Geometry in Latin, Arabic, and English, from between 1482 and 1847. We have a note, handwritten by quantum physicist Erwin Schödinger, about why students shouldn’t fear exams.

I returned to the Dibner one day this spring. Lilla and I fetched out manuscripts and books related to quantum physics and thermodynamics. “Hermann Weyl” labeled one folder.

Weyl contributed to physics and mathematics during the early 1900s. I first encountered his name when studying particle physics. The Dibner, we discovered, owns a proof for part of his 1928 book Gruppentheorie und Quantenmechanik. Weyl appears to have corrected a typed proof by hand. He’d handwritten also spin matrices.

Electrons have a property called “spin.” Spin resembles a property of yours, your position relative to the Earth’s center. We represent your position with three numbers: your latitude, your longitude, and your distance above the Earth’s surface. We represent electron spin with three blocks of numbers, three $2 times 2$ matrices. Today’s physicists write the matrices as2

$S_x = beginbmatrix 0 & 1 \ 1 & 0 endbmatrix , , quad S_y = beginbmatrix 0 & -i \ i & 0 endbmatrix , , quad textand quad S_z = beginbmatrix -1 & 0 \ 0 & 1 endbmatrix , .$

We needn’t write these matrices. We could represent electron spin with different $2 times 2$ matrices, so long as the matrices obey certain properties. But most physicists choose the above matrices, in my experience. We call our choice “a convention.”

Weyl chose a different convention:

$S_x = beginbmatrix 1 & 0 \ 0 & -1 endbmatrix , , quad S_y = beginbmatrix 0 & 1 \ 1 & 0 endbmatrix , , quad textand quad S_z = beginbmatrix 0 & i \ -i & 0 endbmatrix , .$

The difference surprised me. Perhaps it shouldn’t have: Conventions change. Approaches to quantum physics change. Weyl’s matrices differ from ours little: Permute our matrices and negate one matrix, and you recover Weyl’s.

But the electron-spin matrices play a role, in quantum physics, like the role played by T. Rex in paleontology exhibits: All quantum scientists recognize electron spin. We illustrate with electron spin in examples. Students memorize spin matrices in undergrad classes. Homework problems feature electron spin. Physicists have known of electron spin’s importance for decades. I didn’t expect such a bedrock to have changed its trappings.

How did scientists’ convention change? When did it? Why? Or did the convention not change—did Weyl’s contemporaries use today’s convention, and did Weyl stand out?

A partially typed, partially handwritten, proof of a book by Hermann Weyl.

I intended to end this article with these questions. I sent a draft to John Preskill, proposing to post soon. But he took up the questions like a knight taking up arms.

Wolfgang Pauli, John emailed, appears to have written the matrices first. (Physicist call the matrices “Pauli matrices.”) A 1927 paper by Pauli contains the notation used today. Paul Dirac copied the notation in a 1928 paper, acknowledging Pauli. Weyl’s book appeared the same year. The following year, Weyl used Pauli’s notation in a paper.

No document we know of, apart from the Dibner proof, contains the Dibner-proof notation. Did the notation change between the proof-writing and publication? Does the Dibner hold the only anomalous electron-spin matrices? What accounts for the anomaly?

If you know, feel free to share. If you visit DC, drop Lilla and Morgan a line. Bring a research project. Bring a class. Bring zeal for the past. You might find yourself holding a time capsule by Galileo.

Dibner librarian Lilla Vekerdy and a former intern

With thanks to Lilla and Morgan for their hospitality, time, curiosity, and expertise. With thanks to John for burrowing into the Pauli matrices’ history.

1I continue to count myself as part of the Dibner community. Part of me refuses to leave.

2I’ll omit factors of $hbar / 2 , .$